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Karnataka CET 2015 Key Answers, Maths ,Physics,Chemistry and Biology

Karnataka Examination Authority has conducted Common Entrance Test on May 12 and 13th. Our experts has solved the question papers and given the Key Answers.
Please find KCET 2015 Chemistry Key Answers.








CHEMISTRY
[Code :D2]



1.
Number of possible alkynes with formula C 5 H8 is
6.    On heating potassium permanganate, one of the


(1)
4
(2)
2
following compound is not obtained :


(1)
MnO2
(2)
O2


(3)
5
(4)
3

Ans:
(4)


(3)
K 2 MnO4
(4)
MnO

2.
Glycogen is


Ans:
(4)




(1)
structurally very much similar to amylopectin
7.    The salt which responds to dilute and concentrated


(2)
a polymer of   -D-glucose units
H 2 SO4 is




(3)
structurally similar to amylopectin but extensively




(1)
Na 2SO4
(2)
CaF2



branched




(4)
a structural polysaccharide
(3)
Na 3 PO4
(4)
Ba(NO 3 )2

Ans:
(3)


Ans:
(4)



3.    How many ions per molecule are produced in the
8.    Half life period of a first order reaction is 10 min.


solution when Mohr salt is dissolved in excess of
Starting with initial concentration 12 M. the rate after


water?


20 min is




(1)
6
(2) 4
(1)
0.0693   3 M min-1
(2)
0.0693 M min-1


(3)
10
(4) 5
(3)
0.0693   4 M min-1
(4)
0.693  3 M min-1

Ans:
(4)


Ans:
(1)



4.    Which of the following curve is in accordance with



Freundlich adsorption isotherm?

















x
m

x
m
(1)
log
(2)
log


log p


p

x
m

x
m



(3)
log
(4)
log







log p





p

Ans:
(1)
















dryether


H 2 O



5.



Br  MgA
B.














H



The product ‘B’ is







(1)





OH
(2)




OH











(3)





(4)




MgBr











Ans:
(1)















9.    Which of the following aqueous solution has the
highest freezing point ?


(1)
0.1 M NaCl
(2)
0.1 M Sucrose

(3) 0.01 M Na 2 SO4     (4) 0.01 M NaCl

Ans:     (4)

10.    0.30 g of an organic compound containing C, H and Oxygen on combustion yields 0.44 g CO2 and 0.18 g

H 2O . If one mol of compound weighs 60, then molecular formula of the compound is

(1)
C 4 H 6 O
(2)
CH 2O
(3)
C 2 H 4 O2
(4)
C 3 H 8O
Ans:
(3)



11.    For one of the element various successive ionization enthalpies (in kJ mol 1 ) are given below :


























1810



14,820









The element is




(1)
Al
(2)
Si
(3)
Mg
(4)
P
Ans:
(1)

















12.    The aqueous solution of following salt will have the lowest pH :

(1)
NaCl O2
(2)
NaC l O3
(3)
NaCl O4
(4)
NaC l O
Ans:
(3)



13.  One of the following is an essential amino acid.

(1)
Isoleucine
(2)
Tyrosine
(3)
Serine
(4)
Cysteine
Ans:
(1)



14.    The formation of cyanohydrin from a ketone is an example of

(1)  Electrophilic addition

(2)  Nucleophilic substitution

(3)  Electrophilic substitution

(4)  Nucleophilic addition

Ans:     (4)

15.    100 cm3 of 1 M CH3COOH was mixed with 100 cm3 of 2 M CH3OH to form an ester. The change in the initial rate if each solution is diluted with equal volume of water would be

(1)
0.5 times
(2)
2 times
(3)
0.25 times
(4)
4 times
Ans:
(3)



16.    How many Coulombs of electricity are required for the oxidation of one mol of water to dioxygen?
(1)
1.93  105 C
(2)
9.65  104 C
(3)
19.3  105 C
(4)
1.93  104 C
Ans:
(1)



17.    Cheilosis and digestive disorders are due to the deficiency of

(1)
Riboflavin
(2)
Thiamine
(3)
Pyridoxine
(4)
Ascorbic acid
Ans:
(1)



18.    One of the following amide will not undergo Hoffmann bromamide reaction :

(1)
C 6 H 5 CONH 2
(2)
CH 3 CONH2
(3)
CH 3 CH 2 CONH2
(4)
CH 3 CONHCH3
Ans:
(4)


19.  lodoform can be prepared from all, except
(1)
propan-l-ol
(2)
propan-2-ol
(3)
acetophenone
(4)
butan-2-one
Ans:
(1)




20.   The arrangement of following compounds :

i.      bromomethane

ii.     bromoform

iii.    chloromethane

iv.   dibromomethane

In the increasing order of their boiling point is

(1)  ii < iii < i < iv

(2)  iii < i < iv < ii

(3)  i < ii < iii < iv

(4)  iv < iii < i < ii

Ans: (2)

21.    The complex ion having minimum magnitude of 0 (CFSE) is

3
(1)   Co Cl 6

3

(2)   Cr  CN 6

3

(3)   Cr  H 2O 6

3

(4)   Co  NH3  6

Ans:     (1)

22.   Which of the following colloids cannot be easily coagulated ?

(1)  Macromolecular colloids

(2)  Lyophobic colloids

(3)  Irreversible colloids

(4)  Multimolecular colloids

Ans:     (1)

23.  After adding non-volatile solute freezing point of

water decreases to -0.186
°C. Calculate   Tb if
K f
1.86 K kg mol-1 and Kb = 0.521 K kg mol-1
(1)
1.86
(2)
0.521
(3)
0.0186
(4)
0.0521
Ans:
(4)



24.   Which of the following compound of Xenon has pyramidal geometry ?

(1)  XeO3

(3)  XeF4

Ans:     (1)
































25.
Ans:(1)















26.
Ans:(1)












27.What  amount of dioxygen (in gram) contains

1.81022  molecules ?

(1)  9.60

(2)  0.0960

(3)  96.0

(4)  0.960

Ans:     (4)

28.    The pair of compound which cannot exist together in solution is

(1)    NaHCO3  and Na 2 CO3

(2)    NaHCO3  and NaOH

(3)    Na 2 CO3  and NaOH

(4)    NaHCO3 and H 2O

Ans:     (2)












29. Ans:(1)










30.   Arrange the following compounds in the increasing order of their acidic strength :

i.
m-nitrophenol
ii.
m-cresol
iii.
phenol
iv.
m-chlorophenol

(1)  ii < iii < iv < i

(2)  iii < ii <i < iv

(3)  ii < iii < i < iv

(4)  ii < iv < iii < i

Ans: (1)

31.  In the reaction S
3
O
2
SO    2x kj and




2



3








SO 2
1
O 2SO 3     y kj






2








heat of formation of SO2
is


(1)
2x – y


(2)
x + y

(3)
2x + y


(4)
x – y













Ans:     (Bonus)

Correct answer is (–2x) + y

32.   Which of the following is not true?

(1)  Prontosil is not converted into sulphanilamide in the body.

(2)  Erythromycin is a bacteriostatic antibiotic.

(3)  Vancomycillin is a broad spectrum antibiotic.

(4)  Ampicillin is not a natural antibiotic.

Ans:     (1)
















33.    Using MOT, compare O2 and O2 species and choose the incorrect option.

(1)    O2  is diamagnetic while O2  is paramagnetic.

(2)   O2 have higher bond order than O2 .

(3)  Both O2 and O2   are  paramagnetic.

(4)   O2  is less stable.

Ans:     (1)

34.    Which of the following compound the “C - H” bond with the lowest bond dissociation energy?

(1)  n-pentane

(2)  Toluene

(3)  2, 2-dimethyl propane

(4)  Benzene

Ans:     (2)

35.    The correct statement is

(1)  There is maximum p p   back bonding in BF3

(2)  BF3 is the strongest Lewis acid among the other boron halides.

(3)  There is minimum p p  back bonding in BF3

(4)  BI3 is the weakest Lewis acid among the boron halides.

Ans:     (1)

36.   Acetic acid is treated with Ca OH 2 and the product so obtained is subjected to dry distillation.The Final

product is


(1)
propanone
(2)
ethanal
(3)
ethanol
(4)
propanal

Ans:     (1)






37. Ans: (3)
38.Ans: (3) 
39.Ans:(3)
40.  Ans:(1)
41.  Ans:(1)

































42. Ans: (4)


43. Ans:(1)




44. Ans:(3)








45. Ans:(2)
 46. Ans:(4)
 47. Ans:(3)
 48. Ans:(4)
 49. Ans:(3)
50. Ans(1)
51. Ans(1)
52. Ans(1) 
53. Ans(2)
54. Ans(4)
55. Ans(1) 
56. Ans(4)
57. Ans(4)
58. Ans(3) 
59. Ans(4)
60. Ans(3) 

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